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(CYCLOPENTADIENYL)[N,N-DIMETHYL-N'-(2-P
Кат. №: 794139-100MG
Производитель: Sigma-Aldrich
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Товар оформляется под заказ
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(CYCLOPENTADIENYL)[N,N-DIMETHYL-N'-(2-P
Кат. №: 794139-100MG
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description
General description
(η5 -Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.[1]
Application
Catalyst mediates the transformation of alkynes to alcohols through an anti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.
Packaging
100 mg in glass bottle
Other Notes
A Highly Active and Air-Stable Ruthenium Complex for the Ambient Temperature Anti-Markovnikov Reductive Hydration of Terminal Alkynes
Related Categories
Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts Quality Level
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