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"DEUTERIUM OXIDE, ""100"" (MIN. 99.990 ATO&"
Кат. №: 191701-10G
Производитель: Sigma-Aldrich
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Печать
"DEUTERIUM OXIDE, ""100"" (MIN. 99.990 ATO&"
Кат. №: 191701-10G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description
General description
Deuterium oxide (D2O) is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies. Various thermodynamic properties (such as intermolecular vibrational frequencies, energy of the hydrogen bond, free energy, enthalpy and entropy) of liquid deuterium oxide have been evaluated. Ionization constant for D2O (in the range of 5-50°C), pK values (at 25°C) and enthalpy, entropy, heat capacity change (for the dissociation of D2O) have been reported.
Application
Deuterium oxide may be used:
• To prepare trifluoroacetic acid-d by reacting with trifluoroacetic anhydride.
• As a deuteration agent for primary and secondary alcohols at the β-carbon position via H/D exchange reaction in the presence of ruthenium catalyst.
• Along with hexamethyldisilane as a deuterium transfer reagent for alkynes to form (E)-1,2-dideuterioalkenes in the presence of a palladium complex.
Packaging
10 g in ampule
10×0.25, 10×0.5 mL in ampule
Related Categories
"Ultra" and "Extra" Enriched D2O, Alphabetical Listings, D, Deuterium oxide, NMR Solvents,
NMR Solvents and Reagents, NMR Solvents for High Resolution NMR, Solvent by Application, Solvents, Spectroscopy Solvents (IR, NMR, UV/Vis), Stable Isotopes
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