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DIISOBUTYLALUMINUM HYDRIDE, 1.0M SOLUTIO
Кат. №: 214973-800ML
Производитель: Sigma-Aldrich
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DIISOBUTYLALUMINUM HYDRIDE, 1.0M SOLUTIO
Main image
Кат. №: 214973-800ML
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Main image
Печать
DIISOBUTYLALUMINUM HYDRIDE, 1.0M SOLUTIO
Кат. №: 214973-800ML
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description General description Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis. Application Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into α-fluoro-α,β-unsaturated esters in the presence of fluorocarboalkoxy-substituted dialkyl phosphonate anions via Horner-Wadsworth-Emmons reaction. It can be used in the multi-step synthesis of (S)-2-methyl tetrahydropyridine-N-oxide, a key structural moiety of bio-active compounds like himbacine and solenopsin-A. Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. Packaging 1 L in Sure/Seal™ 100, 800 mL in Sure/Seal™
Related Categories
Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.
Description General description Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis. Application Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into α-fluoro-α,β-unsaturated esters in the presence of fluorocarboalkoxy-substituted dialkyl phosphonate anions via Horner-Wadsworth-Emmons reaction. It can be used in the multi-step synthesis of (S)-2-methyl tetrahydropyridine-N-oxide, a key structural moiety of bio-active compounds like himbacine and solenopsin-A. Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. Packaging 1 L in Sure/Seal™ 100, 800 mL in Sure/Seal™
Related Categories
Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.