Description General description BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl (p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported. Application (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It may be employed as chiral catalyst for allylation of N-tosyl α-imino esters. Takasago Ligands and Complexes for Asymmetric Reactions Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated ester Reactant serving as a precursor for: • Catalysts used for reductive amination of ketones • Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives • Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones • CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters • BINAP Pt Dications for cation trapping Packaging 100, 500 mg in amber glass bottle Legal Information Sold in collaboration with Takasago for research purposes only.