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(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'
Кат. №: 295825-1G
Производитель: Sigma-Aldrich
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Товар оформляется под заказ
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(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'
Кат. №: 295825-1G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description
Application
2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls.
Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids.
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates
Packaging
1, 5 g in glass bottle
250 mg in glass insert
Related Categories
Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chemicals for the synthesis of candidate COVID-19 treatments, Chiral Catalysts, Ligands, and Reagents,
Nelfinavir Mesylate, Privileged Ligands and Complexes
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