Перейти к контенту
Main image
Печать
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'
Кат. №: 295825-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Печать
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'
Main image
Кат. №: 295825-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Main image
Печать
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'
Кат. №: 295825-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description Application 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls. Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids. Reactant involved in: • Enantioselective and diastereoselective unpoled carbonyl allylation • Syntehsis of organophophine oxides as anittumor agents • SN2 halogenation of hydroxy groups • Synthesis of BINAP complexes • Studies of conformational flexibility of BINAP chelates Packaging 1, 5 g in glass bottle 250 mg in glass insert
Related Categories
Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chemicals for the synthesis of candidate COVID-19 treatments, Chiral Catalysts, Ligands, and Reagents, Nelfinavir Mesylate, Privileged Ligands and Complexes More... Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.
Description Application 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls. Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids. Reactant involved in: • Enantioselective and diastereoselective unpoled carbonyl allylation • Syntehsis of organophophine oxides as anittumor agents • SN2 halogenation of hydroxy groups • Synthesis of BINAP complexes • Studies of conformational flexibility of BINAP chelates Packaging 1, 5 g in glass bottle 250 mg in glass insert
Related Categories
Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chemicals for the synthesis of candidate COVID-19 treatments, Chiral Catalysts, Ligands, and Reagents, Nelfinavir Mesylate, Privileged Ligands and Complexes More... Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.