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SCANDIUM(III) TRIFLATE, 99%
Кат. №: 418218-5G
Производитель: Sigma-Aldrich
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SCANDIUM(III) TRIFLATE, 99%
Кат. №: 418218-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description
General description
Scandium(III) triflate is an important catalyst for Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates.
Application
Scandium(III) triflate was used as catalyst in the following studies:
• Hydrothiolation reaction of aromatic and aliphatic thiols.
• Selective two-electron reduction of O2 by ferrocene derivatives.
• Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water.
• Synthesis of β-cyanoketones.
It was also used with triethylsilane to reductively open functionalized pyranoside rings and in the key step of synthesis of bullvalone via a stabilized sulfur ylide.
Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Related Categories
Catalysis and Inorganic Chemistry, Chemical Synthesis, Scandium Catalysts More... Quality Level
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