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SCANDIUM(III) TRIFLATE, 99%
Кат. №: 418218-5G
Производитель: Sigma-Aldrich
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SCANDIUM(III) TRIFLATE, 99%
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Кат. №: 418218-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Main image
Печать
SCANDIUM(III) TRIFLATE, 99%
Кат. №: 418218-5G
Производитель: Sigma-Aldrich
Кол-во:
Цена по запросу
Товар оформляется под заказ
Description General description Scandium(III) triflate is an important catalyst for Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates. Application Scandium(III) triflate was used as catalyst in the following studies: • Hydrothiolation reaction of aromatic and aliphatic thiols. • Selective two-electron reduction of O2 by ferrocene derivatives. • Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water. • Synthesis of β-cyanoketones. It was also used with triethylsilane to reductively open functionalized pyranoside rings and in the key step of synthesis of bullvalone via a stabilized sulfur ylide. Packaging 1, 5 g in glass bottle 250 mg in glass bottle
Related Categories
Catalysis and Inorganic Chemistry, Chemical Synthesis, Scandium Catalysts More... Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.
Description General description Scandium(III) triflate is an important catalyst for Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates. Application Scandium(III) triflate was used as catalyst in the following studies: • Hydrothiolation reaction of aromatic and aliphatic thiols. • Selective two-electron reduction of O2 by ferrocene derivatives. • Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water. • Synthesis of β-cyanoketones. It was also used with triethylsilane to reductively open functionalized pyranoside rings and in the key step of synthesis of bullvalone via a stabilized sulfur ylide. Packaging 1, 5 g in glass bottle 250 mg in glass bottle
Related Categories
Catalysis and Inorganic Chemistry, Chemical Synthesis, Scandium Catalysts More... Quality Level
Дорогой клиент, на сайте внедрена нейросеть для сбора информации о товаре. Это может привести к незначительным расхождениям в характеристиках продукции.