Description General description Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) participates in the synthesis of azepane.[12] Crystal structure of Pd2(dba)3 has been determined by three-dimensional X-ray data. Crystals of Pd2(dba)3 are reported to crystalize in triclinic system.[13] It is widely used Pd(0) source in Pd-mediated transformations.[14] Application • Catalyst for Suzuki coupling of aryl chlorides[5] (eq. 1) • Catalyst for Heck coupling of aryl chlorides[5] (eq. 2) • Catalyst for arylation of ketones[6] (eq. 3) • Catalyst for Buchwald-Hartwig amination of aryl halides[7] (eq. 4) • Catalyst for fluorination of allylic chlorides[8] (eq. 5) • Catalyst for β-arylation of carboxylic esters[1] (eq. 6) • Catalyst for carbonylation of 1,1-dichloro-1-alkenes[4] (eq. 7) • Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides[2] (eq. 8) Application Guide for Palladium Catalyzed Cross-Coupling Reactions Reactant involved in: • Synthesis of nanosized palladium phosphides upon interaction with white phosphorous • Preparation of palladium triphenylphosphine carbonyl cluster complexes • Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions • Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes Catalyst for: • Suzuki cross-coupling reactions • PCN- and PCS-pincer palladium complex catalyzed tandem allylation Packaging 1, 5, 25, 50, 100, 500 g in glass bottle 500 mg in glass bottle